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Total synthesis of Bipinnatin J:
Reference: Roethle, P. A.; Trauner, D. Org. Lett. 2006, 8, 345 DOI
Keywords: Al-Vinyl -> Vinyl-I --- Alkyl-OH -> Aldehyde --- Enal -> Allyl-OH --- Allyl-OH -> Allyl-Br --- Mitsunobu -> Br --- Alkyne Carboalumination --- Li-Alkynyl+Aldehyde --- Enyne reaction --- Lactone-5 --- Wittig-ketomethyl -> Enal --- Pd/Sn-Aryl+Vinyl-X --- Stille coupling --- Nozaki-Hiyama coupling --- Cr-Allyl+Aldehyde --- Li/H -> Li-Furyl
Reagents: AlMe3 --- ZrCp2Cl2 --- I2 --- Dess-Martin --- Alkynyl-Li --- LiNiPr2 --- RuCp(NCMe)3PF6 --- Camphor sulfonic acid --- Ph3P=C(Me)-C(O)R --- BH4-Na+ --- Pd(PPh3)4 --- CuI --- Fluoride, cesium --- NBS --- CrCl2 --- NiCl2 --- LiN(OMe)Me --- BuLi(n) --- SnMe3-Cl

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