| Reference: | Sharp, L. A.; Zard, S. Z. Org. Lett. 2006, 8, 831-834 |
| Keywords: | Aryl-OH -> Aryl-OMe --- Friedel-Crafts Acylation --- Lactam-5 --- Radical cyclization(Aminyl) --- Birch alkylation --- Fischer Indole --- Hydrogenolysis Ketone --- Ketone -> CH2 --- CarboxAmide -> Amine --- EC-CarboxAmide/Ketone+B-H --- CarboxEster enolate+Bromoacetate --- Decarboxylation Krapcho --- Mechanism |
| Reagents: | AcCl --- H2, Pd --- Carbonate, potassium --- Li°/NH3 --- HCl, H2O --- O=C(OR)Cl --- Benzoyl chloride --- HSnBu3 --- 9-BBN-H --- Chloride, lithium --- Hydrazine, phenyl --- BH4-Na+ --- Bromoacetate --- DMF (solvent) |