| Reference: | Avery, M. A.; Jennings-White, C.; Chong, W. K. M. Tetrahedron Lett. 1987, 28, 4629-4632 DOI |
| Keywords: | Ketone-α-S(O)nR -> Ketone Ketone -> Hydrazone Li-Vinyl+CarboxAmide Al-SiR3+Enal O-H -> O-C(O)R Claisen-Ireland CarboxAcid -> CarboxEster Williamson esterification O-H -> O-Alkyl CarboxEster enolate+Alkyl-X CarboxEster -> CarboxAcid Ketal -> Ketone Sulfide -> Sulfoxide Ketosulfoxide dianion Ketone enolate+Alkyl-X Shapiro reaction Mechanism Ozonolysis |
| Reagents: | LiNiPr2 Disulfide, phenyl Al(Hg) Hydrazine, tosyl BuLi(n) DMF (react) Al(SiMe3)3 DMAP LiNiPrCy Me2SO4 LiNiPrCy Hydroxide, potassium Oxalic acid O3 Perbenzoic acid, 3-chloro |