| Reference: | Menche, D.; Hassfels, J.; Li, J.; Mayer, K.; Rudolph, S. J. Org. Chem. 2009, 74, 7220. DOI |
| Keywords: | EnoateEster -> Allyl-OH • Allyl-OH -> Enal • CarboxEster -> Carboxamide • Abiko-Masamune Aldol • B-Aldol • O-H -> O-Alkyl • B-Aldol • O-PMB -> O-H • Alkyl-OH -> Aldehyde • O-SiMe2tBu -> O-H • Carbene • CarboxEster enolate+Alkyl-X • CarboxAmide(Weinreb)+Mg-Alkyl • Dehydration -> Enone • Pd-Heck coupling • HWE -> EnoateEster • |
| Reagents: | CHI3 • Hydroxide, potassium • AlH4-Li+ • MnO2 • BOTf(c-Hx)2 • Alkyl-MgX • Acetic anhydride • DBU • NEt3 • Ag2O • MeMgBr • BCl(c-Hx)2 • NEt3 • PdCl2(PPh3)2 • BOP • DDQ • DMSO, (COCl)2 • NEt3 • NaH • DMAP • HF·Py • |