| Reference: | Va, P.; Roush, W. R. J. Am. Chem. Soc. 2006, 128, 15960. DOI |
| Keywords: | Alkyl-OH -> Aldehyde-α-OR Mg-Vinyl+Aldehyde Hydroboration Alkene Alkyl-OH -> Aldehyde Corey-Fuchs Diol-1,2 cleavage B-Allyl+Aldehyde O-H -> O-SiEt3 O-PMB -> O-H Ketal -> Diol Hydrostannation Alkyne Pd/Sn-Vinyl+Vinyl-X Stille coupling RCM -> Lactone Lactone-15+ Claisen-Johnson Fritsch-Buttenberg-Wiechell Aldehyde -> Alkyne Protecting group - Diene Si-Alkyl -> H-Alkyl Sn-Vinyl -> Vinyl-I CarboxEster -> Aldehyde Si-Allyl+Aldehyde Ether-5 O-H -> O-SiEt3 Si-Alkyl -> H-Alkyl |
| Reagents: | DMSO, (COCl)2 Vinyl-MgX Orthoacetate AlHiBu2 9-BBN-H H2O2, NaOH DMSO, Py·SO3 PPh3=CBr2 BuLi(n) Acetic acid Periodate, sodium Allyl-B(tartrate) HSiEt3 BF3·OEt2 Fluoride, Bu4N+ HSiEt3 DDQ Benzoyl chloride, 2,4,6-trichloro Ceric ammonium nitrate Grubbs I SnBu3-AlEt2 CuCN NIS Acetic acid Vinyl-SnR3 Pd(PPh3)4 CuCl Imidazole DMF (solvent) |