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Total synthesis of Aloperine, iso:
Reference: Brosius, A. D.; Overman, L. E. J. Org. Chem. 1997, 62, 440
Keywords: Allyl-OH -> Enone --- N-Boc -> N-H --- N-H -> N-Troc --- N-Troc -> N-H --- Selenoxide-Ei -> Allyl-OH --- Epoxide -> Allyl-OH --- Pd/B-Alkyl+Vinyl-X --- Suzuki coupling --- Alkene Carboiodination --- Amine-6 --- Dehydroiodination -> Ene --- Enone -> Enone-α-Halo --- Dehydration -> Ene --- CarboxAmide -> Amine --- Furst-Plattner diaxial --- Epoxidation, peracid --- ConjAdd Amine --- Amine-6
Reagents: TfOH --- DBU --- Perbenzoic acid, 3-chloro --- NaSePh --- H2O2 --- RuO4-Pr4N+, NMO --- I2, Py --- 9-BBN-R --- PdCl2(dppf) --- CF3CO2H --- Hydroxide, sodium --- AlH4-Li+ --- O=C(OR)Cl --- Troc-Cl --- POCl3 --- Cd/Pb --- Iodide, Bu4N+

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