| Reference: | Bonjoch, J.; Sole, D.; Garcia-Rubio, S.; Bosch, J. J. Am. Chem. Soc. 1997, 119, 7230. DOI |
| Keywords: | Si-Propargyl+Enone, Intram --- Amine-6 --- N-Me -> N-CO2R --- Ketone -> Enolsilane --- Ketone -> α-Selenoketone --- Reductive amination, B-H --- Amine-5 --- Selenoxide-Ei -> Enone-6 --- Ketone -> Enone --- Claisen acylation, Mander --- Ketone enolate+Mander --- Amine+Propargyl-I --- Hydrogenation-NO2 --- Aryl-NO2 -> Aryl-NH2 --- Hydrogenation-Allene --- Ozonolysis |
| Reagents: | Propargyl-Si --- BF3 --- LiNiPr2 --- H2, Pd --- O3 --- NH2Me --- O=C(OR)Cl --- NH(SiMe3)2 (HMDS) --- SiMe3-I --- PhSeCl --- O3 --- Propargyl-I --- Carbonate, potassium --- HCl --- H2, Pd --- O=C(OR)CN --- NHiPr2 --- BH3CN-Na+ |