| Reference: | Rubottom, G. M.; Juve, H. D. Jr. J. Org. Chem. 1983, 48, 422 |
| Keywords: | Enolsilane -> Ketone enolate --- Enone -> Enolsilane --- Dehydrobromination -> Enone --- CarboxEster enolate+Ketone --- Aldol-Li -> Aldol --- Ketone -> Ketone-α-Br --- Dehydration -> EneLactone --- Ketone -> Enolsilane --- Enone -> Enolsilane --- Ketone -> Ketone-α-OH --- Enolsilane+MCPBA --- Rubottom oxidation |
| Reagents: | LiNiPr2 --- SiMe3-Cl --- MeLi --- Br2 --- LiNiPr2 --- SiMe3-Cl --- Perbenzoic acid, 3-chloro --- HF·NEt3 --- Ac2O --- LiNiPr2 --- SOCl2 --- DMAP --- Bromide, lithium --- Carbonate, lithium --- DMF (solvent) |