| Reference: | Munchhof, M. J.; Heathcock, C. H. J. Org. Chem. 1994, 59, 7566. DOI |
| Keywords: | CarboxAmide(Evans) -> CarboxEster --- CarboxEster -> Alkyl-OH --- O-H -> O-CPh3 --- Luche reduction --- Enone -> Allyl-OH --- O-H -> O-SiMe2tBu --- Alkyl-OH -> Aldehyde --- Alkyl-OH -> Ketone --- O-THP -> O-H --- O-SiMe2tBu -> O-H --- CarboxAmide(Weinreb)+Li-Vinyl --- Claisen-Ireland --- Aldol-B-Evans --- 2,3-Sigmatropic Sulfoxide --- Lactone enolate+Aldehyde --- Aldol-Li -> Aldol --- Lactone-6 --- CarboxAcid -> CarboxAmide(Weinreb) --- CarboxAmide(Evans) -> CarboxEster |
| Reagents: | LiOCH2Ph --- AlHiBu2 --- Ph3CCl --- LiNiPr2, HMPA --- SiMe2tBu-Cl --- O=C(Im)2 --- Vinyl-Li --- BH4-Na+, CeCl3 --- Perbenzoic acid, 3-chloro --- P(OMe)3 --- SiMe2tBu-OTf --- ZnBr2 --- DMSO, Py·SO3 --- Dess-Martin --- Acetic acid --- BHsBu3-Li+ --- Diazomethane --- HF·Py --- DMAP --- NMe(OMe)-H |