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Total synthesis of 5-Desoxy-Leucotriene D:
Reference: Corey, E. J.; Hoover, D. J. Tetrahedron Lett., 1982, 23, 3463. DOI
Keywords: O-H -> O-C(O)R • Allyl-X -> Allyl-SR • Sulfide -> Sulfoxide • O-C(O)R -> O-H • CarboxEster -> CarboxAcid • 2,3-Sigmatropic Sulfoxide • Pummerer • Acetal(thio) -> Enal • Wittig-alkyl -> Ene-cis • Allyl-OH -> Allyl-SR • Mechanism •
Reagents: BuLi(n) • Benzoyl chloride • Acetic acid, trifluoro • Acetate, sodium • HS-Ph • Carbonate, potassium • Perbenzoic acid, 3-chloro • Carbonate, calcium • HgCl2 • Carbonate, potassium • MeSO2Cl, NEt3 • Carbonate, potassium • Hydroxide, lithium •

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