| Reference: | Hu, T.; Corey, E. J. Org. Lett. 2002, 4, 2441. DOI |
| Keywords: | Silyl ketone Brook • Ketone enolate+Allyl-X • Pd-Enolate allylation • Tsuji-Trost allylation • McMurry coupling • EC-Allyl-Br/Carbonate+Enolate • Tsuji-Trost allylation • Pd-Enolate allylation • Ozonolysis • RC-Alkene/Alkene+O3 • Mechanism • Ketone -> Ketone-α-Br • Ketone-α-S(O)nR -> Ketone • |
| Reagents: | Propenyl-Li • Allyl-Br • TASF • SiMe3-OTf • PhSO2Na • Pd(PPh3)4 • Al(Hg) • O3 • Zn/Cu • SiMe3-OTf • NEtiPr2 • Carbonate, calcium • Pd2(dba)3 • Me2S • Acetate, potassium • |