| Reference: | Brenneman, G. B.; Martin, S. F. Org. Lett. 2004, 6, 1329. DOI |
| Keywords: | CarboxEster -> Aldehyde • Alkene cleavage • N-Cbz -> N-H • Enyne metathesis • Li-Alkynyl+Me-X • CarboxAmide -> Ketone • Mg-Alkyl+Carboximide • EC-Carboximide/CarboxEster+Mg-R • EC-CarboxEster/Carbamate+Al-H • Lemieux-Johnson oxidation • Seyferth-Gilbert homologation • Aldehyde -> Alkyne • Reductive amination, Si-H • Amine-5 • |
| Reagents: | Alkyl-MgX • BF3·OEt2 • HSiPh3 • Diazophosphonate • AlHiBu2 • NaN(SiMe3)2 • MeOTf • OsO4 • Periodate, sodium • SiMe3-I • Grubbs II • |