| Reference: | Yang, J.; Wu, H.; Shen, L.; Qin, Y.. J. Am. Chem. Soc. 2007, 129, 13794. DOI |
| Keywords: | CarboxEster -> Alkyl-OH • O-H -> O-SiEt3 • N-H -> N-Me • O-SiEt3 -> O-H • N-H -> N-C(O)OR • Alkene cleavage • Aldehyde -> Oxime • Alkyl-OH -> Aldehyde • Aldehyde -> Oxime • N-H -> N-Boc • N-Boc -> N-H • N-H -> N-C(O)R • Imine -> Amine • Friedel-Crafts Acylation • Staudinger • Diazoketone • Claisen-Ketene acetal • Reductive amination, H2 • Lactam-5 • Reductive amination, H2 • Pd-Heck coupling • N-H -> N-Alkyl • Amine-7 • CarboxAmide -> Imidate • Imidate -> Amidine • Cyclopropane alkylation • Cyclopropanation Diazoketone • Lactone-6 • CarboxEster epimerization • CarboxEster -> Ketene acetal • |
| Reagents: | Oxalyl chloride • AlH4-Li+ • HSiEt3 • MeI • Fluoride, Bu4N+ • Bisulfate, Bu4N+ • Hydrazine, tosyl • TsOH • DBU • CuOTf • PBu3 • O=C(OR)Cl • DMAP • NaH • Allyl-Br • OsO4 • Periodate, sodium • NH2OH • H2, RaNi • Dess-Martin • NH2OH • H2, RaNi • Boc2O • Pd(OAc)2 • P(Tol)3 • NEt3 • TsOH·Py • Et3O+ X- • NEtiPr2 • SiO2 • Acetic acid, trifluoro • Hydroxide, potassium • Acetic anhydride • Carbonate, sodium • NaOMe • DMAP • |