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Total synthesis of Cherylline:
Reference: Hart, D. J.; Cain, P. A.; Evans, D. A. J. Am. Chem. Soc. 1978, 100, 1548. DOI
Keywords: CarboxAmide enolate+Ketone • O-Bn -> O-H • CarboxAmide -> Amine • Ketene+Amine • Peterson -> EnoateAmide • Friedel-Crafts Alkylation • Lactam-6 • Aryl-OMe -> Aryl-OH • Quinone •
Reagents: Ketene, trimethylsilyl • LiNiPr2 • BF3·OEt2 • H2, Pd • AlH4-Li+ • NaS-Et • DMF (solvent) • Tl(NO2)3

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