image

Total synthesis of Bursehemin:
Reference: Baran, P. S.; DeMartino, M. P. Angew. Chem IE. 2006, 45, 7083. DOI
Keywords: CarboxAmide(Evans) -> Alkyl-OH • Lactone-5 • CarboxEster enolate Oxidative coupling • CarboxAmide enolate Oxidative coupling • CarboxAmide enolate(Evans) coupling •
Reagents: LiNiPr2 • Cu(OAc)2 • BH4-Li+ • DBU •

Syntheses Home