| Reference: | Herzon, S. B.; Myers, A. G J. Am. Chem. Soc. 2005, 127, 5342 DOI |
| Keywords: | Saegusa oxidation • Ketone -> Enone • Ketone -> Alkyl-OH(asym) • O-H -> O-SiPh2tBu • Ketal -> Enone • Enone enolate+Allyl-X • ConjAdd M-SR • Lactam-6 • Ketone -> Enamine • N-Boc -> N-H • O-SiPh2tBu -> O-H • Allyl-OH -> Enone • Enone -> Enone-α-Halo • Ullman coupling • Ketone enolate+Me-I • Enamine -> CyanoAmine • Ketone epimerization • Nitrile -> CarboxAcid • Radical cyclization(Acyl) • Nitrone synthesis • |
| Reagents: | LiN(SiMe3)2 • SiMe3-Cl • Pd(OAc)2 • BH3·SMe2 • Corey oxazaborolidine • SiPh2tBu-OTf • Lutidine • H2SO4 • KN(SiMe3)2 • Cyanide, trimethylsilyl • KN(SiMe3)2 • NaOtBu • MeI • Piv-OH • HS-Ph • NEt3 • SiMe3-OTf • Lutidine • HF • Dess-Martin • I2 • DMAP • Pd2(dba)3 • Zn° • NEtiPr2 • NEt3 • |