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Total synthesis of Aloperine, iso:
Reference: Brosius, A. D.; Overman, L. E. J. Org. Chem. 1997, 62, 440. DOI
Keywords: Allyl-OH -> Enone • N-Boc -> N-H • N-H -> N-Troc • N-Troc -> N-H • Selenoxide-Ei -> Allyl-OH • Epoxide -> Allyl-OH • Pd/B-Alkyl+Vinyl-X • Suzuki coupling • Alkene Carboiodination • Amine-6 • Dehydrohalogenation -> Ene • Enone -> Enone-α-Halo • Dehydration -> Ene • CarboxAmide -> Amine • Furst-Plattner diaxial • Epoxidation, peracid • ConjAdd Amine • Amine-6 •
Reagents: TfOH • DBU • Perbenzoic acid, 3-chloro • SePh-Na • H2O2 • RuO4-Pr4N+, NMO • I2, Py • 9-BBN-R • PdCl2(dppf) • Acetic acid, trifluoro • Hydroxide, sodium • AlH4-Li+ • O=C(OR)Cl • Troc-Cl • POCl3 • Cd/Pb • Iodide, Bu4N+

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