| Reference: | Rubottom, G. M.; Juve, H. D. Jr. J. Org. Chem. 1983, 48, 422. DOI |
| Keywords: | Enolsilane -> Ketone enolate • Enone -> Enolsilane • O-H -> O-C(O)R • Dehydrohalogenation -> Enone • CarboxEster enolate+Ketone • Aldol-Li -> Aldol • Ketone -> Ketone-α-Br • Dehydration -> EneLactone • Ketone -> Enolsilane • Enone -> Enolsilane • Ketone -> Ketone-α-OH • Enolsilane+MCPBA • Rubottom oxidation • |
| Reagents: | LiNiPr2 • SiMe3-Cl • MeLi • Bromine • LiNiPr2 • SiMe3-Cl • Perbenzoic acid, 3-chloro • HF·NEt3 • DMAP • LiNiPr2 • SOCl2 • Bromide, lithium • Carbonate, lithium • DMF (solvent) • |